000 04277nam a22004935i 4500
001 978-3-7091-1317-2
003 DE-He213
005 20140220082925.0
007 cr nn 008mamaa
008 121213s2013 au | s |||| 0|eng d
020 _a9783709113172
_9978-3-7091-1317-2
024 7 _a10.1007/978-3-7091-1317-2
_2doi
050 4 _aQD410-412.5
072 7 _aPNND
_2bicssc
072 7 _aSCI013040
_2bisacsh
082 0 4 _a547.05
_223
100 1 _aYamashita, Masahiro.
_eeditor.
245 1 0 _aMaterial Designs and New Physical Properties in MX- and MMX-Chain Compounds
_h[electronic resource] /
_cedited by Masahiro Yamashita, Hiroshi Okamoto.
264 1 _aVienna :
_bSpringer Vienna :
_bImprint: Springer,
_c2013.
300 _aIX, 270 p. 190 illus., 45 illus. in color.
_bonline resource.
336 _atext
_btxt
_2rdacontent
337 _acomputer
_bc
_2rdamedia
338 _aonline resource
_bcr
_2rdacarrier
347 _atext file
_bPDF
_2rda
505 0 _a1 General Intoruduction S. Takaishi and M. Yamashita -- 2 MX-Chain Compounds -- 2.1 Pt(II)-Pt(IV) and Pd(II)-Pd(IV) Mixed-Valence Compounds H. Matsuzaki and H. Okamoto -- 2.2 Ni(III) Mott-Hubbard Compounds S. Takaishi and M. Yamashita -- 2.3 Pd(III) Mott-Hubbard Compounds S. Takaishi and M. Yamashita -- 2.4 Photoinduced Phase Transitions in MX-Chain Compounds H. Matsuzaki and H. Okamoto -- 2.5 Nonlinear Electrical Conductivity, Current Oscillation and Its Control in Halogen-Bridged Nickel(III) Compounds H. Kishida and A. Nakamura -- 2.6 Gigantic Third-Order Optical Nonlinearity of Halogen-Bridged Nickel(III) Compounds H. Kishida and H. Okamoto -- 2.7 Theory of MX-Chain Compounds K. Iwano -- 3 MMX-Chain Compounds -- 3.1 Crystal Structures and Properties of MMX-Chain Compounds Based on Dithiocarboxylato-Bridged Dinuclear Complexes M. Mitsumi -- 3.2 POP-Type MMX-Chain Compounds with Binary Counter-Cations and Vapochromism H. Iguchi, S. Takaishi and M. Yamashita -- 3.3 Photoinduced Phase Transitions in MMX-Chain Compounds H. Matsuzaki and H. Okamoto -- 3.4 Theory of MMX-Chain Compounds K. Yonemitsu.
520 _aThis is the first book to comprehensively address the recent developments in both the experimental and theoretical aspects of quasi-one-dimensional halogen-bridged mono- (MX) and binuclear metal (MMX) chain complexes of Pt, Pd and Ni. These complexes have one-dimensional electronic structures, which cause the various physical properties as well as electronic structures. In most MX-chain complexes, the Pt and Pd units are in M(II)-M(IV) mixed valence or charge density wave (CDW) states due to electron-phonon interactions, and Ni compounds are in Ni(III) averaged valence or Mott-Hubbard states due to the on-site Coulomb repulsion. More recently, Pd(III) Mott-Hubbard (MH) states have been realized in the ground state by using the chemical pressure. Pt and Pd chain complexes undergo photo-induced phase transitions from CDW to MH or metal states, and Ni chain complexes undergo photo-induced phase transitions from MH to metal states. Ni chain complexes with strong electron correlations show tremendous third-order optical nonlinearity and nonlinear electrical conductivities. They can be explained theoretically by using the extended Peierls-Hubbard model. For MMX-chain complexes, averaged valence, CDW, charge polarization, and alternating charge polarization states have been realized by using chemical modification and external stimuli, such as temperature, photo-irradiation, pressure, and water vapor. All of the electronic structures and phase transitions can be explained theoretically.
650 0 _aChemistry.
650 0 _aChemistry, inorganic.
650 0 _aChemistry, Organic.
650 0 _aBiochemistry.
650 0 _aOptical materials.
650 1 4 _aChemistry.
650 2 4 _aOrganometallic Chemistry.
650 2 4 _aOptical and Electronic Materials.
650 2 4 _aMedicinal Chemistry.
650 2 4 _aInorganic Chemistry.
700 1 _aOkamoto, Hiroshi.
_eeditor.
710 2 _aSpringerLink (Online service)
773 0 _tSpringer eBooks
776 0 8 _iPrinted edition:
_z9783709113165
856 4 0 _uhttp://dx.doi.org/10.1007/978-3-7091-1317-2
912 _aZDB-2-CMS
999 _c98967
_d98967