000			03346nam a22005535i 4500
001			978-3-642-39115-6
003			DE-He213
005			20140220082914.0
007			cr nn 008mamaa
008			130804s2013 gw | s |||| 0|eng d
020			_a9783642391156 _9978-3-642-39115-6
024	7		_a10.1007/978-3-642-39115-6 _2doi
050		4	_aQD505
072		7	_aPNRD _2bicssc
072		7	_aSCI013060 _2bisacsh
082	0	4	_a541.395 _223
100	1		_aWu, Peng. _eauthor.
245	1	0	_aMWW-Type Titanosilicate _h[electronic resource] : _bSynthesis, Structural Modification and Catalytic Applications to Green Oxidations / _cby Peng Wu, Hao Xu, Le Xu, Yueming Liu, Mingyuan He.
264		1	_aBerlin, Heidelberg : _bSpringer Berlin Heidelberg : _bImprint: Springer, _c2013.
300			_aVIII, 125 p. 79 illus., 25 illus. in color. _bonline resource.
336			_atext _btxt _2rdacontent
337			_acomputer _bc _2rdamedia
338			_aonline resource _bcr _2rdacarrier
347			_atext file _bPDF _2rda
490	1		_aSpringerBriefs in Molecular Science, _x2191-5407
505	0		_aIntroduction -- Synthesis of Ti-MWW zeolite -- Post-synthesis modification of Ti-MWW: a door to diversity -- Catalytic properties of Ti-MWW in selective oxidation reactions -- Conclusions and Prospects.
520			_aThis book provides a comprehensive review of a new generation of selective oxidation titanosilicate catalysts with the MWW topology (Ti-MWW) based on the research achievements of the past 12 years. It gives an overview of the synthesis, structure modification and catalytic properties of Ti-MWW. Ti-MWW can readily be prepared by means of direct hydrothermal synthesis with crystallization-supporting agents, using dual-structure-directing agents and a dry-gel conversion technique. It also can be post-synthesized through unique reversible structure transformation and liquid-phase isomorphous substitution. The structural conversion of Ti-MWW into the materials usable for processing large molecules is summarized. Taking advantage of the structure diversity of the lamellar precursor of Ti-MWW, it can be fully or partially delaminated, and undergo interlayer silylation to obtain a novel structure with larger porosity. In the selective oxidation (alkene epoxidation and ketone/aldehyde ammoximation) with hydrogen peroxide or organic peroxide as an oxidant, the unique catalytic properties of Ti-MWW are described in comparison to conventional titanosilicates such as TS-1 and Ti-Beta.
650		0	_aChemistry.
650		0	_aChemistry, Physical organic.
650		0	_aChemical engineering.
650		0	_aCatalysis.
650		0	_aEnvironmental chemistry.
650	1	4	_aChemistry.
650	2	4	_aCatalysis.
650	2	4	_aEnvironmental Chemistry.
650	2	4	_aIndustrial Chemistry/Chemical Engineering.
650	2	4	_aPhysical Chemistry.
700	1		_aXu, Hao. _eauthor.
700	1		_aXu, Le. _eauthor.
700	1		_aLiu, Yueming. _eauthor.
700	1		_aHe, Mingyuan. _eauthor.
710	2		_aSpringerLink (Online service)
773	0		_tSpringer eBooks
776	0	8	_iPrinted edition: _z9783642391149
830		0	_aSpringerBriefs in Molecular Science, _x2191-5407
856	4	0	_uhttp://dx.doi.org/10.1007/978-3-642-39115-6
912			_aZDB-2-CMS
999			_c98394 _d98394