000 02686nam a22004695i 4500
001 978-3-642-33173-2
003 DE-He213
005 20140220082854.0
007 cr nn 008mamaa
008 121026s2013 gw | s |||| 0|eng d
020 _a9783642331732
_9978-3-642-33173-2
024 7 _a10.1007/978-3-642-33173-2
_2doi
050 4 _aQD415-436
072 7 _aPNN
_2bicssc
072 7 _aSCI013040
_2bisacsh
082 0 4 _a547
_223
100 1 _aShahzad, Sohail Anjum.
_eauthor.
245 1 0 _aNovel Selenium-Mediated Rearrangements and Cyclisations
_h[electronic resource] /
_cby Sohail Anjum Shahzad.
264 1 _aBerlin, Heidelberg :
_bSpringer Berlin Heidelberg :
_bImprint: Springer,
_c2013.
300 _aXX, 190 p. 238 illus., 6 illus. in color.
_bonline resource.
336 _atext
_btxt
_2rdacontent
337 _acomputer
_bc
_2rdamedia
338 _aonline resource
_bcr
_2rdacarrier
347 _atext file
_bPDF
_2rda
490 1 _aSpringer Theses, Recognizing Outstanding Ph.D. Research,
_x2190-5053 ;
_v77
505 0 _aGeneral Introduction on Selenium.- The Synthesis of Novel Dihydronaphthalenes and Benzofluorenes -- The Synthesis of Naphthalenes and Biaryls -- Synthesis of Isocoumarins and Dihydroisocoumarins.- Experimental Section.
520 _aIn his thesis, Sohail Shahzad carefully investigates carbon nucleophiles in selenocyclisations, as well as reaction protocols for performing such reactions catalytically. After a comprehensive introduction to the element selenium, the author goes on to report the synthesis of several substrates for carbocyclisation reactions and the use of selenium reagents for the preparation of dihydronaphthalenes. Further chapters detail electrophilic selenium-mediated reactions, and novel strategies using selenium catalysts together with stoichiometric amounts of hypervalent iodine reagents as oxidants to convert stilbene carbosylic acids into the corresponding isocoumarins. This thesis outlines some excellent new synthetic routes which will be useful tools for synthetic organic chemistry in the future.
650 0 _aChemistry.
650 0 _aChemistry, inorganic.
650 0 _aChemistry, Organic.
650 1 4 _aChemistry.
650 2 4 _aOrganic Chemistry.
650 2 4 _aInorganic Chemistry.
650 2 4 _aChemistry/Food Science, general.
710 2 _aSpringerLink (Online service)
773 0 _tSpringer eBooks
776 0 8 _iPrinted edition:
_z9783642331725
830 0 _aSpringer Theses, Recognizing Outstanding Ph.D. Research,
_x2190-5053 ;
_v77
856 4 0 _uhttp://dx.doi.org/10.1007/978-3-642-33173-2
912 _aZDB-2-CMS
999 _c97345
_d97345