000 03399nam a22005295i 4500
001 978-4-431-54625-2
003 DE-He213
005 20140220082525.0
007 cr nn 008mamaa
008 131216s2014 ja | s |||| 0|eng d
020 _a9784431546252
_9978-4-431-54625-2
024 7 _a10.1007/978-4-431-54625-2
_2doi
050 4 _aQD478
072 7 _aTBN
_2bicssc
072 7 _aSCI050000
_2bisacsh
082 0 4 _a541.2
_223
100 1 _aNishikawa, Michihiro.
_eauthor.
245 1 0 _aPhotofunctionalization of Molecular Switch Based on Pyrimidine Ring Rotation in Copper Complexes
_h[electronic resource] /
_cby Michihiro Nishikawa.
264 1 _aTokyo :
_bSpringer Japan :
_bImprint: Springer,
_c2014.
300 _aXII, 123 p. 105 illus., 23 illus. in color.
_bonline resource.
336 _atext
_btxt
_2rdacontent
337 _acomputer
_bc
_2rdamedia
338 _aonline resource
_bcr
_2rdacarrier
347 _atext file
_bPDF
_2rda
490 1 _aSpringer Theses, Recognizing Outstanding Ph.D. Research,
_x2190-5053
505 0 _aGeneral introduction -- Details of Molecular Bistability Based on Pyrimidine Ring Rotation in Copper(I) Complexes -- Dual emission caused by ring rotational isomerization of a copper(I) complex -- Repeatable Copper(II)/(I) Redox Potential Switching Driven Visible Light-Induced Coordinated Ring Rotation -- Concluding remarks.
520 _aThis book provides a detailed description of photofunctionalization of molecular switch based on pyrimidine ring rotational isomerization in copper complexes bearing two bidentate ligands. The most important features of this work focus on the properties associated with the rotational isomerization based on the two possible coordination geometries at the copper center derived from two nitrogen atoms on the unsymmetrically substituted pyrimidine ring. The functions of systems such as dual emission and redox potential switching based on photo-driven rotation will be of particular interest to readers. Both the functions and the procedures for proving these phenomena are beneficial for the development of more functionalized systems based on material science, molecular science, nanoscience, nanotechnology, electrochemistry, photochemistry, coordination chemistry, physical chemistry, and related disciplines. The finding elucidated here holds promise for handling the photoprocesses of metal complexes, valid for both applications and novel properties. This system is expected make it possible to extract an electrochemical potential response from molecular switches, aiming to simulate the five senses of human beings at a single molecular level.
650 0 _aChemistry.
650 0 _aChemistry, inorganic.
650 0 _aChemistry, Organic.
650 0 _aNanochemistry.
650 0 _aNanotechnology.
650 1 4 _aChemistry.
650 2 4 _aNanochemistry.
650 2 4 _aNanotechnology.
650 2 4 _aOrganometallic Chemistry.
650 2 4 _aElectrochemistry.
650 2 4 _aInorganic Chemistry.
650 2 4 _aElectrochemistry.
710 2 _aSpringerLink (Online service)
773 0 _tSpringer eBooks
776 0 8 _iPrinted edition:
_z9784431546245
830 0 _aSpringer Theses, Recognizing Outstanding Ph.D. Research,
_x2190-5053
856 4 0 _uhttp://dx.doi.org/10.1007/978-4-431-54625-2
912 _aZDB-2-CMS
999 _c93716
_d93716