000			02889nam a22004815i 4500
001			978-3-642-39756-1
003			DE-He213
005			20140220082519.0
007			cr nn 008mamaa
008			131108s2014 gw | s |||| 0|eng d
020			_a9783642397561 _9978-3-642-39756-1
024	7		_a10.1007/978-3-642-39756-1 _2doi
050		4	_aQD450-882
072		7	_aPNR _2bicssc
072		7	_aSCI013050 _2bisacsh
082	0	4	_a541 _223
100	1		_aRen, Zefeng. _eauthor.
245	1	0	_aState-to-State Dynamical Research in the F+H2 Reaction System _h[electronic resource] / _cby Zefeng Ren.
264		1	_aBerlin, Heidelberg : _bSpringer Berlin Heidelberg : _bImprint: Springer, _c2014.
300			_aXII, 77 p. 64 illus., 21 illus. in color. _bonline resource.
336			_atext _btxt _2rdacontent
337			_acomputer _bc _2rdamedia
338			_aonline resource _bcr _2rdacarrier
347			_atext file _bPDF _2rda
490	1		_aSpringer Theses, Recognizing Outstanding Ph.D. Research, _x2190-5053
505	0		_aIntroduction -- Hydrogen Atom Rydberg Tagging Time-of-Flight Crossed Molecular Beam Apparatus -- Dynamical Resonances in F+H2 Reactions -- The Non-Adiabatic Effects in F(2P)+D2→DF+D.
520			_aThis thesis addresses two important and also challenging issues in the research of chemical reaction dynamics of F+H2 system. One is to probe the reaction resonance and the other is to determine the extent of the breakdown of the Born-Oppenheimer approximation (BOA) experimentally. The author introduces a state-of-the-art crossed molecular beam-scattering apparatus using a hydrogen atom Rydberg "tagging" time-of-flight method, and presents thorough state-to-state experimental studies to address the above issues. The author also describes the observation of the Feshbach resonance in the F+H2 reaction, a precise measurement of the differential cross section in the F+HD reaction, and validation of a new accurate potential energy surface with spectroscopic accuracy. Moreover, the author determines the reactivity ratio between the ground state F(2P3/2) and the excited state F*(2P1/2) in the F+D2 reaction, and exploits the breakdown of BOA in the low collision energy.
650		0	_aChemistry.
650		0	_aSpectroscopy.
650		0	_aChemistry, Physical organic.
650	1	4	_aChemistry.
650	2	4	_aPhysical Chemistry.
650	2	4	_aAtomic/Molecular Structure and Spectra.
650	2	4	_aTheoretical and Computational Chemistry.
650	2	4	_aSpectroscopy/Spectrometry.
710	2		_aSpringerLink (Online service)
773	0		_tSpringer eBooks
776	0	8	_iPrinted edition: _z9783642397554
830		0	_aSpringer Theses, Recognizing Outstanding Ph.D. Research, _x2190-5053
856	4	0	_uhttp://dx.doi.org/10.1007/978-3-642-39756-1
912			_aZDB-2-CMS
999			_c93358 _d93358