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001 978-90-481-2866-2
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007 cr nn 008mamaa
008 110120s2011 ne | s |||| 0|eng d
020 _a9789048128662
_9978-90-481-2866-2
024 7 _a10.1007/978-90-481-2866-2
_2doi
050 4 _aQD410-412.5
072 7 _aPNND
_2bicssc
072 7 _aSCI013040
_2bisacsh
082 0 4 _a547.05
_223
100 1 _aCazin, Catherine S.J.
_eeditor.
245 1 0 _aN-Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis
_h[electronic resource] /
_cedited by Catherine S.J. Cazin.
264 1 _aDordrecht :
_bSpringer Netherlands :
_bImprint: Springer,
_c2011.
300 _aXVI, 340 p.
_bonline resource.
336 _atext
_btxt
_2rdacontent
337 _acomputer
_bc
_2rdamedia
338 _aonline resource
_bcr
_2rdacarrier
347 _atext file
_bPDF
_2rda
490 1 _aCatalysis by Metal Complexes,
_x0920-4652 ;
_v32
505 0 _a1. N-Heterocyclic Carbenes – An Introductory Overview -- 2. N-Heterocyclic Carbene Complexes in Additions to Multiple Bonds -- 3. N-Heterocyclic Carbene Complexes in Olefin Metathesis -- 4. N-Heterocyclic Carbene Complexes in Polymerisation, Oligomerisation and Telomerisation Reactions -- 5. N-Heterocyclic Carbene Complexes in Cyclisation Reactions -- 6. N-Heterocyclic Carbene Complexes in Cross-Coupling Reactions -- 7. N-Heterocyclic Carbene Complexes in Arylation Reactions Other than Cross-Couplings -- 8. N-Heterocyclic Carbene Complexes in Dehalogenation Reactions -- 9. N-Heterocyclic Carbene Complexes in Reactions Involving Carbon Monoxide -- 11. N-Heterocyclic Carbene Complexes in Other Transition Metal Mediated Reactions -- 12. N-Heterocyclic Carbenes in Organocatalysis -- 13. N-Heterocyclic Carbene Complexes - Decomposition Pathways -- 14. N-Heterocyclic Carbene Complexes in Industrial Processes.
520 _aN-Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis features all catalytic reactions enabled by N-heterocyclic carbenes (NHCs), either directly as organocatalysts or as ligands for transition metal catalysts. An explosion in the use of NHCs has been reported in the literature during the past seven years making this comprehensive overview highly apropos. The book begins with an introductory overview of NHCs which could have been subtitled all you need to know about NHCs. The main body of the book is dedicated to applications of NHCs in catalysis. In addition to the success stories of NHCs in metathesis, NHCs in cross coupling and more recently NHCs in organocatalysis, all other less publicized areas are also covered. As the success of NHCs is generally attributed to their potential to stabilize metal centres, the inclusion of a chapter on the decomposition of NHC catalysts is pertinent. The book closes with a chapter describing the applications of NHCs in industrial processes, which is the first coverage of its kind, and brings a unique industrial context to this book. Included in this book: Historical aspects of NHCs Synthetic pathways to NHC precursors, free NHCs and complexes Methods of characterisation of NHCs and related complexes Electronic properties of NHCs Steric properties of NHCs and models for their description NHCs for metathesis and cross-coupling reactions NHCs as organocatalysts NHC Transition-Metal mediated oxidations, additions to multiple bonds, polymerisation and oligomerisation, cyclisations, direct arylations, reactions involving CO, C-F and C-H bond activation, … Decomposition of NHC-containing catalysts Industrial applications involving NHC-containing catalysts N-Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis provides a fresh view of NHCs since most contributors are young emerging researchers in the field of homogeneous catalysis using NHCs. This group of contributors is complemented by highly established academic researchers and an industrialist. This book is comprehensive, from the basic features of NHCs to the latest advances, hence it is suitable for both the novice and the expert.
650 0 _aChemistry.
650 0 _aChemistry, Organic.
650 0 _aCatalysis.
650 1 4 _aChemistry.
650 2 4 _aOrganometallic Chemistry.
650 2 4 _aCatalysis.
650 2 4 _aOrganic Chemistry.
710 2 _aSpringerLink (Online service)
773 0 _tSpringer eBooks
776 0 8 _iPrinted edition:
_z9789048128655
830 0 _aCatalysis by Metal Complexes,
_x0920-4652 ;
_v32
856 4 0 _uhttp://dx.doi.org/10.1007/978-90-481-2866-2
912 _aZDB-2-CMS
999 _c108924
_d108924