000 03994nam a22005295i 4500
001 978-3-642-19872-4
003 DE-He213
005 20140220083758.0
007 cr nn 008mamaa
008 110630s2011 gw | s |||| 0|eng d
020 _a9783642198724
_9978-3-642-19872-4
024 7 _a10.1007/978-3-642-19872-4
_2doi
050 4 _aQD380-388
072 7 _aPNNP
_2bicssc
072 7 _aTEC055000
_2bisacsh
082 0 4 _a541.2254
_223
100 1 _aCaneba, Gerard.
_eauthor.
245 1 0 _aEmulsion-based Free-Radical Retrograde-Precipitation Polymerization
_h[electronic resource] /
_cby Gerard Caneba, Yadunandan Dar.
264 1 _aBerlin, Heidelberg :
_bSpringer Berlin Heidelberg :
_bImprint: Springer,
_c2011.
300 _aXIII, 191p. 104 illus.
_bonline resource.
336 _atext
_btxt
_2rdacontent
337 _acomputer
_bc
_2rdamedia
338 _aonline resource
_bcr
_2rdacarrier
347 _atext file
_bPDF
_2rda
505 0 _aPart I - FRRPP theory -- Calculations to probe FRRPP behavior of PMAA-MAA-Water system -- Closed-form estimation of reactive polymer domain size for FRRPP control -- Molecular weight considerations in FRRPP behavior -- LCST-UCST-based Copolymerization -- Unsteady-State Mathematical Modeling/Computer Simulation of FRRPP Behavior -- Part II - Emulsion FRRPP (EFRRPP) -- Initial approach -- Modified approach -- Impact of process parameters on EFRRPP -- Radical-containing polymer emulsions -- Control experiments to test auto-polymerization of PS and BA -- Part III – Supplementary Topics -- Cloudpoint Studies of PMMA-MMA-Pentane Systems -- PMMA-PBA from Emulsion PMMA-MMA-Pentane Systems -- Low-VOC Latex Paints and Coatings -- Oil Spill Control from Emulsion-based FRRPP Foaming Surfactant Systems -- Polymer Modification of VA-AA-based Copolymer Emulsions -- Oil Dispersants from FRRPP-based Surfactants.
520 _aThis monograph is a follow-up material to the first FRRPP book by Gerard Caneba in 2009. It includes additional conceptual results, implementation of the FRRPP process in emulsion media to produce various block copolymers, and other FRRPP-related supplementary topics. Conceptual topics include the application of the quantitative analysis presented in the first FRRPP monograph for the occurrence of the FRRPP process to the polysterene-styrene-ether (PS-S-Ether) and poly(methacrylic acid)-methacrylic acid-water (PMAA-MAA-Water) systems, as well as extensions through unsteady state analysis of the occurrence of flat temperature profiles.  Also, the generalization of the quantitative analysis is done to consider molecular weight effects, especially based on changes of the phase envelope to an hourglass type. Topics in implementation of the FRRPP process from pre-emulsions of monomers and the solvent/precipitant are highlighted.  Additional FRRPP topics are included in this monograph that pertain to more recent efforts of Gerard Caneba, such as  oil spill control, oil dispersant system, and caustic sludge remediation from emulsion-based FRRPP materials, hydrolysis of vinyl acetate-acrylic acid-based copolymers, and other polymer modification studies from FRRPP-based emulsions.
650 0 _aChemistry.
650 0 _aChemistry, Physical organic.
650 0 _aPolymers.
650 0 _aChemical engineering.
650 0 _aIndustrial engineering.
650 0 _aNanotechnology.
650 1 4 _aChemistry.
650 2 4 _aPolymer Sciences.
650 2 4 _aIndustrial and Production Engineering.
650 2 4 _aNanotechnology.
650 2 4 _aPhysical Chemistry.
650 2 4 _aIndustrial Chemistry/Chemical Engineering.
650 2 4 _aTheoretical and Computational Chemistry.
700 1 _aDar, Yadunandan.
_eauthor.
710 2 _aSpringerLink (Online service)
773 0 _tSpringer eBooks
776 0 8 _iPrinted edition:
_z9783642198717
856 4 0 _uhttp://dx.doi.org/10.1007/978-3-642-19872-4
912 _aZDB-2-CMS
999 _c107664
_d107664