000			03185nam a22004815i 4500
001			978-1-4419-9647-3
003			DE-He213
005			20140220083730.0
007			cr nn 008mamaa
008			110609s2011 xxu| s |||| 0|eng d
020			_a9781441996473 _9978-1-4419-9647-3
024	7		_a10.1007/978-1-4419-9647-3 _2doi
050		4	_aQD505
072		7	_aPNRD _2bicssc
072		7	_aSCI013060 _2bisacsh
082	0	4	_a541.395 _223
100	1		_aSpruell, Jason M. _eauthor.
245	1	4	_aThe Power of Click Chemistry for Molecular Machines and Surface Patterning _h[electronic resource] / _cby Jason M. Spruell.
264		1	_aNew York, NY : _bSpringer New York, _c2011.
300			_aXVII, 119p. 64 illus., 61 illus. in color. _bonline resource.
336			_atext _btxt _2rdacontent
337			_acomputer _bc _2rdamedia
338			_aonline resource _bcr _2rdacarrier
347			_atext file _bPDF _2rda
490	1		_aSpringer Theses
505	0		_aKinetic and Thermodynamic Approaches for the Efficient Formation of Mechanical Bonds -- Efficient Templated Synthesis of Donor–Acceptor Rotaxanes using Click Chemistry -- A One-Pot Synthesis of Constitutionally Unsymmetrical Rotaxanes Using Sequential Cu(I)-Catalyzed Azide–Alkyne Cycloadditions -- Heterogeneous Catalysis through Microcontact Printing -- Heterogeneous Catalysis of a Copper-Coated Atomic Force Microscopy Tip for Direct-Write Click Chemistry -- A Push-Button Molecular Switch -- Highly Stable TTF Radical Dimers in a Five-State [3]Catenane.
520			_aThe union of covalent and noncovalent chemistries manifested in the mechanical bond represents one of the great chemical triumphs of the last half century. However, until recently, the preparation of mechanically interlocked compounds has often been an inefficient and limiting process. This thesis provides a detailed account of the great strides taken to increase the synthetic accessibility of donor-acceptor mechanically interlocked molecules by the application of highly efficient and ultramild chemical transformations during their template-directed synthesis. These new departures in synthesis have indeed played a transformative role in that more complex, higher-order, and functional architectures – once only a dream – are now comfortably within reach. Specifically, the formation of mechanical bonds in higher order rotaxanes and catenanes has become ever easier through the use of highly efficient click chemistries. The resulting mechanically interlocked compounds are functional molecular media for a host of applications including information storage, mechanical actuation, and drug release.
650		0	_aChemistry.
650		0	_aCatalysis.
650		0	_aNanochemistry.
650		0	_aNanotechnology.
650	1	4	_aChemistry.
650	2	4	_aCatalysis.
650	2	4	_aNanochemistry.
650	2	4	_aNanotechnology.
710	2		_aSpringerLink (Online service)
773	0		_tSpringer eBooks
776	0	8	_iPrinted edition: _z9781441996466
830		0	_aSpringer Theses
856	4	0	_uhttp://dx.doi.org/10.1007/978-1-4419-9647-3
912			_aZDB-2-CMS
999			_c106092 _d106092