000 03010nam a22004575i 4500
001 978-3-642-32099-6
003 DE-He213
005 20140220083323.0
007 cr nn 008mamaa
008 120905s2012 gw | s |||| 0|eng d
020 _a9783642320996
_9978-3-642-32099-6
024 7 _a10.1007/978-3-642-32099-6
_2doi
050 4 _aQD410-412.5
072 7 _aPNND
_2bicssc
072 7 _aSCI013040
_2bisacsh
082 0 4 _a547.05
_223
100 1 _aGøgsig, Thomas M.
_eauthor.
245 1 0 _aNew Discoveries on the β-Hydride Elimination
_h[electronic resource] /
_cby Thomas M. Gøgsig.
264 1 _aBerlin, Heidelberg :
_bSpringer Berlin Heidelberg :
_bImprint: Springer,
_c2012.
300 _aXVII, 122 p. 125 illus., 57 illus. in color.
_bonline resource.
336 _atext
_btxt
_2rdacontent
337 _acomputer
_bc
_2rdamedia
338 _aonline resource
_bcr
_2rdacarrier
347 _atext file
_bPDF
_2rda
490 1 _aSpringer Theses, Recognizing Outstanding Ph.D. Research,
_x2190-5053
505 0 _aBackground -- Palladium 1,2-migration in the Heck reaction -- Palladium 1,2-migration in the Negishi and Kumada coupling -- Stoichiometric studies on the palladium 1,2-migration -- Heteroaromatic tosylates in the regio-selective Heck reaction -- Cationic intermediates in the Ni(0)-catalyzed Heck reaction -- Carbonylative Heck reaction -- Conclusions.
520 _aThe work presented in Thomas M. Gøgsig's thesis deals with the discovery of new metal-catalyzed transformations ranging from Kumada-, Heck- and Suzuki-type reactions. The thesis starts with a formidable introduction to Pd-catalyzed cross-coupling reactions. New results have been obtained on: (i) Pd-catalyzed 1,2-migration reactions, (ii) Pd-catalyzed Heck reactions employing heteroaromatic tosylates, (iii) Ni-catalyzed Heck reactions, and (iv) Pd-catalyzed carbonylative Heck reactions. Metal-catalyzed cross-coupling reactions are today a highly competititve field (the 2010 Nobel Prize in Chemistry was awarded "for palladium-catalyzed cross couplings in organic synthesis", the 2001 and 2005 Nobel Prizes in closely related fields). Thomas M. Gøgsig obtained new results in his thesis that will help to improve the outcome of catalytic processes and improve their scope. The results will thus become key references for tomorrow's new applications. All chapters include insightful discussions and in-depth descriptions of the key principles of these new discoveries.
650 0 _aChemistry.
650 0 _aChemistry, Organic.
650 0 _aCatalysis.
650 1 4 _aChemistry.
650 2 4 _aOrganometallic Chemistry.
650 2 4 _aCatalysis.
710 2 _aSpringerLink (Online service)
773 0 _tSpringer eBooks
776 0 8 _iPrinted edition:
_z9783642320989
830 0 _aSpringer Theses, Recognizing Outstanding Ph.D. Research,
_x2190-5053
856 4 0 _uhttp://dx.doi.org/10.1007/978-3-642-32099-6
912 _aZDB-2-CMS
999 _c103450
_d103450