000 02513nam a22004815i 4500
001 978-3-642-27573-9
003 DE-He213
005 20140220083309.0
007 cr nn 008mamaa
008 120109s2012 gw | s |||| 0|eng d
020 _a9783642275739
_9978-3-642-27573-9
024 7 _a10.1007/978-3-642-27573-9
_2doi
050 4 _aQD505
072 7 _aPNRD
_2bicssc
072 7 _aSCI013060
_2bisacsh
082 0 4 _a541.395
_223
100 1 _aShao, Lixiong.
_eauthor.
245 1 0 _aChemical Transformations of Vinylidenecyclopropanes
_h[electronic resource] /
_cby Lixiong Shao, Jianmei Lu, Min Shi.
264 1 _aBerlin, Heidelberg :
_bSpringer Berlin Heidelberg,
_c2012.
300 _aX, 69p. 83 illus., 6 illus. in color.
_bonline resource.
336 _atext
_btxt
_2rdacontent
337 _acomputer
_bc
_2rdamedia
338 _aonline resource
_bcr
_2rdacarrier
347 _atext file
_bPDF
_2rda
490 1 _aSpringerBriefs in Molecular Science,
_x2191-5407
505 0 _aIntroduction -- Lewis or Brønsted acid-mediated transformations of VDCPs -- Transition metal-catalyzed transformation of VDCPs -- Miscellaneous analogues -- Concluding remarks and perspectives of VDCPs.
520 _aModern organic synthesis has paid much attention to the chemistry of small carbocycles. Vinylidenecyclopropanes (VDCPs), which have strained cyclopropyl group connected with an allene moiety and yet are thermally stable and reactive substances in organic chemistry, are versatile intermediates in organic synthesis. In this volume, Dr. Lixiong Shao, Dr. Jianmei Lu and Prof. Dr. Min Shi review their investigations on the chemistry of VDCPs, mainly including the preparation, the reactivities upon treatment with Lewis or Brønsted acid, as well as transition metal catalysts and some other miscellaneous analogues. The contributions aroused a renaissance of cationic intermediates in the chemistry of VDCPs.
650 0 _aChemistry.
650 0 _aChemistry, Organic.
650 0 _aCatalysis.
650 1 4 _aChemistry.
650 2 4 _aCatalysis.
650 2 4 _aOrganometallic Chemistry.
700 1 _aLu, Jianmei.
_eauthor.
700 1 _aShi, Min.
_eauthor.
710 2 _aSpringerLink (Online service)
773 0 _tSpringer eBooks
776 0 8 _iPrinted edition:
_z9783642275722
830 0 _aSpringerBriefs in Molecular Science,
_x2191-5407
856 4 0 _uhttp://dx.doi.org/10.1007/978-3-642-27573-9
912 _aZDB-2-CMS
999 _c102622
_d102622