000 02770nam a22004815i 4500
001 978-3-642-24361-5
003 DE-He213
005 20140220083303.0
007 cr nn 008mamaa
008 120103s2012 gw | s |||| 0|eng d
020 _a9783642243615
_9978-3-642-24361-5
024 7 _a10.1007/978-3-642-24361-5
_2doi
050 4 _aQD415-436
072 7 _aPNN
_2bicssc
072 7 _aSCI013040
_2bisacsh
082 0 4 _a547
_223
100 1 _aQiu, Zaozao.
_eauthor.
245 1 0 _aLate Transition Metal-Carboryne Complexes
_h[electronic resource] :
_bSynthesis, Structure, Bonding, and Reaction with Alkenes and Alkynes /
_cby Zaozao Qiu.
264 1 _aBerlin, Heidelberg :
_bSpringer Berlin Heidelberg,
_c2012.
300 _aXVIII, 133p. 121 illus., 11 illus. in color.
_bonline resource.
336 _atext
_btxt
_2rdacontent
337 _acomputer
_bc
_2rdamedia
338 _aonline resource
_bcr
_2rdacarrier
347 _atext file
_bPDF
_2rda
490 1 _aSpringer Theses
505 0 _aIntroduction -- Nickel-1,2-o-Carboryne Complexes -- Nickel-Mediated Coupling Reactions of 1,2-o-Carboryne with Alkenes -- Nickel-Mediated/Catalyzed Three-Component Cycloaddition Reaction of 1,2-o-Carboryne/Arynes, Alkenes, and Alkynes -- Nickel-Catalyzed Regioselective [2+2+2] Cycloaddition of 1,2-o-Carboryne with Alkynes -- Palladium/Nickel-Cocatalyzed [2+2+2] Cycloaddition of 1,3-o-Carboryne with Alkynes -- Conclusion -- Experimental Section.
520 _aIn this thesis, Zaozao Qiu shows that transition metals can mediate or catalyze cycloaddition and coupling reactions of carboryne with alkynes or alkenes. These reactions afford benzocarboranes, alkenylcarboranes or dihydrobenzocarboranes, and are powerful strategies to assemble useful complex molecules in a single operation from very simple precursors. Carboranes have many applications in medicine. However, their unique structures make derivatization difficult and until now limited efficient synthetic methods to obtain functional carborane materials have restricted their application. This work breaks new ground in metal-carboryne chemistry and will have a significant impact on synthetic, cluster and materials chemistry.  
650 0 _aChemistry.
650 0 _aChemistry, inorganic.
650 0 _aChemistry, Organic.
650 0 _aBiochemistry.
650 1 4 _aChemistry.
650 2 4 _aOrganic Chemistry.
650 2 4 _aInorganic Chemistry.
650 2 4 _aMedicinal Chemistry.
710 2 _aSpringerLink (Online service)
773 0 _tSpringer eBooks
776 0 8 _iPrinted edition:
_z9783642243608
830 0 _aSpringer Theses
856 4 0 _uhttp://dx.doi.org/10.1007/978-3-642-24361-5
912 _aZDB-2-CMS
999 _c102279
_d102279