000 03189nam a22004695i 4500
001 978-3-642-21622-0
003 DE-He213
005 20140220083258.0
007 cr nn 008mamaa
008 120110s2012 gw | s |||| 0|eng d
020 _a9783642216220
_9978-3-642-21622-0
024 7 _a10.1007/978-3-642-21622-0
_2doi
050 4 _aQD450-801
072 7 _aPNRP
_2bicssc
072 7 _aSCI013050
_2bisacsh
082 0 4 _a541.2
_223
100 1 _aBaev, Alexei K.
_eauthor.
245 1 0 _aSpecific Intermolecular Interactions of Organic Compounds
_h[electronic resource] /
_cby Alexei K. Baev.
264 1 _aBerlin, Heidelberg :
_bSpringer Berlin Heidelberg :
_bImprint: Springer,
_c2012.
300 _aXVIII, 434 p. 157 illus.
_bonline resource.
336 _atext
_btxt
_2rdacontent
337 _acomputer
_bc
_2rdamedia
338 _aonline resource
_bcr
_2rdacarrier
347 _atext file
_bPDF
_2rda
505 0 _aReverse Dative Bond in Organic Compounds, Molecular Complexes and Inconsistency of the sp3-Hybridization Model with Respect to Carbon Atom -- Nontraditional Approaches to Thermodynamic Analysis of Liquid Organic Compounds -- Types and Energies of Specific Intermolecular Interactions in Ethers and Organic Cyclic Oxides -- Specific Intermolecular Interactions of Ketones -- Types and Energies of Hydrogen Bonds and Specific Intermolecular Interactions in Alcohols -- Specific Intermolecular Interactions and H-Bonds in Aldehydes and Esters -- Types and Energies of Specific Intermolecular Interactions in Carboxylic Acids -- Specific Intermolecular Interactions in Hydrocarbons.
520 _aProf. Baev presents in his book the development of the thermodynamic theory of specific intermolecular interactions for a wide spectrum of organic compounds: ethers, ketones, alcohols, carboxylic acids, and hydrocarbons. The fundamentals of an unconventional approach to the theory of H-bonding and specific interactions are formulated based on a concept of pentacoordinate carbon atoms. New types of hydrogen bonds and specific interactions are substantiated and on the basis of the developed methodology their energies are determined. The system of interconnected quantitative characteristics of the stability of specific intermolecular interactions is presented. The laws of their transformations are discussed and summarized. The new concept of the extra stabilizing effect of isomeric methyl groups on the structure and stability of organic molecules is introduced and the destabilization action on specific interactions is outlined.
650 0 _aChemistry.
650 0 _aChemistry, Organic.
650 0 _aChemistry, Physical organic.
650 0 _aChemical engineering.
650 1 4 _aChemistry.
650 2 4 _aTheoretical and Computational Chemistry.
650 2 4 _aOrganic Chemistry.
650 2 4 _aPhysical Chemistry.
650 2 4 _aIndustrial Chemistry/Chemical Engineering.
710 2 _aSpringerLink (Online service)
773 0 _tSpringer eBooks
776 0 8 _iPrinted edition:
_z9783642216213
856 4 0 _uhttp://dx.doi.org/10.1007/978-3-642-21622-0
912 _aZDB-2-CMS
999 _c101990
_d101990