Synthesis in the Key of Catellani: Norbornene-Mediated ortho C–H Functionalization -- Mechanistic Considerations in the Development and Use of Azine, Diazine and Azole N-Oxides in Palladium-Catalyzed Direct Arylation -- Palladium and Copper Catalysis in Regioselective, Intermolecular Coupling of C–H and C–Hal Bonds -- Pd-Catalyzed C–H Bond Functionalization on the Indole and Pyrrole Nucleus -- Remote C–H Activation via Through-Space Palladium and Rhodium Migrations -- Palladium-Catalyzed Aryl–Aryl Bond Formation Through Double C–H Activation -- Palladium-Catalyzed Allylic C–H Bond Functionalization of Olefins -- Ruthenium-Catalyzed Direct Arylations Through C–H Bond Cleavages -- Rhodium-Catalyzed C–H Bond Arylation of Arenes -- Cross-Dehydrogenative Coupling Reactions of sp3-Hybridized C–H Bonds -- Functionalization of Carbon–Hydrogen Bonds Through Transition Metal Carbenoid Insertion -- Metal-Catalyzed Oxidations of C–H to C–N Bonds.

Table of Contents - Synthesis in the Key of Catellani: Norbornene-Mediated ortho C–H Functionalization - Mechanistic Considerations in the Development and Use of Azine, Diazine and Azole N-Oxides in Palladium-Catalyzed Direct Arylation - Palladium and Copper Catalysis in Regioselective, Intermolecular Coupling of C–H and C–Hal Bonds - Pd-Catalyzed C–H Bond Functionalization on the Indole and Pyrrole Nucleus - Remote C–H Activation via Through-Space Palladium and Rhodium Migrations - Palladium-Catalyzed Aryl–Aryl Bond Formation Through Double C–H Activation - Palladium-Catalyzed Allylic C–H Bond Functionalization of Olefins - Ruthenium-Catalyzed Direct Arylations Through C–H Bond Cleavages - Rhodium-Catalyzed C–H Bond Arylationof Arenes - Cross-Dehydrogenative Coupling Reactions of sp3-Hybridized C–H Bonds - Functionalization of Carbon–Hydrogen Bonds Through Transition Metal Carbenoid Insertion - Metal-Catalyzed Oxidations of C–H to C–N Bonds